Complexation of heterocyclic azo compounds with transition metal ions as found by the laser-induced desorption/ionization method
- Авторы: Grechnikov A.1, Borodkov A.1, Simakina Y.1, Arabova Z.1, Mikhailova A.1, Kuz’min I.1, Dedkov Y.1, Minin V.2
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Учреждения:
- V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
- N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Выпуск: Том 65, № 12 (2016)
- Страницы: 2789-2794
- Раздел: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/239500
- DOI: https://doi.org/10.1007/s11172-016-1657-8
- ID: 239500
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Аннотация
The Pd, Mn, La, and Rh complexes with the heterocyclic azo compounds were studied by the laser-induced electron transfer desorption/ionization (LETDI) method. The optimum parameters of laser irradiation were found, and the compositions of the complexes were determined. The quantum chemical simulation of the compositions of the complexes was performed on the basis of the data of mass spectrometry. It is shown that laser-induced electron transfer desorption/ionization is an effective tool for the high-sensitive determination and identification of metal complexes.
Об авторах
A. Grechnikov
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: grechnikov@geokhi.ru
Россия, 19 ul. Kosygina, Moscow, 119991
A. Borodkov
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
Россия, 19 ul. Kosygina, Moscow, 119991
Ya. Simakina
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
Россия, 19 ul. Kosygina, Moscow, 119991
Z. Arabova
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
Россия, 19 ul. Kosygina, Moscow, 119991
A. Mikhailova
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
Россия, 19 ul. Kosygina, Moscow, 119991
I. Kuz’min
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
Россия, 19 ul. Kosygina, Moscow, 119991
Yu. Dedkov
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
Россия, 19 ul. Kosygina, Moscow, 119991
V. Minin
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
Россия, 31 Leninsky prosp., Moscow, 119991