On the reaction of nido-carborane with thiourea
- 作者: Anufriev S.1, Erokhina S.1, Sivaev I.1, Bregadze V.1
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隶属关系:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- 期: 卷 65, 编号 11 (2016)
- 页面: 2704-2707
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/239376
- DOI: https://doi.org/10.1007/s11172-016-1638-y
- ID: 239376
如何引用文章
详细
A reaction of the protonated form of 7,8-dicarba-nido-undecaborate anion 7,8-C2B9H13 with thiourea leads to the formation of a mixture of 9- and 10-thiuronium derivatives, the alkaline hydrolysis of which gives a mixture of the corresponding mercapto derivatives of nido-carborane. The alkylation of the latter with benzyl bromide led to a mixture of dibenzylsulfonium derivatives 9-Bn2S-7,8-C2B9H11 and 10-Bn2S-7,8-C2B9H11, which were separated by column chromatography on silica.
作者简介
S. Anufriev
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: sivaev@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
S. Erokhina
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: sivaev@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
I. Sivaev
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: sivaev@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
V. Bregadze
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: sivaev@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991