Synthesis, structure, and properties of a new bifunctional radical cation salt with ferracarborane anion: (BEDT-TTF)2[8,8´-Cl2-3,3´-Fe(1,2-C2B9H10)2]
- 作者: Kazheva O.1, Kravchenko A.2, Aleksandrov G.3, Kosenko I.4, Lobanova I.4, Bregadze V.4, Chudak D.2, Buravov L.1, Protasova S.5, Starodub V.6, Dyachenko O.1
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隶属关系:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- V. N. Karazin Kharkov National University
- N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Institute of Solid State Physics, Russian Academy of Sciences
- Institute of Chemistry, Jan Kochanowski University in Kielce
- 期: 卷 65, 编号 9 (2016)
- 页面: 2195-2201
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238929
- DOI: https://doi.org/10.1007/s11172-016-1567-9
- ID: 238929
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详细
A new radical cation salt of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) with iron(III) bis(1,2-dicarbollide) 8,8´-dichloro derivatives, that is (BEDT-TTF)2[8,8´-Cl2-3,3´-Fe-(1,2-C2B9H10)2], was synthesized. Its electroconducting and magnetic characteristics were studied, molecular and crystal structures were determined. The electroconductivity of crystals at room temperature was σ293 ~5 Ω–1 cm–1, which is close to the corresponding value for the salt of cobalt bis(1,2-dicarbollide) dichloro derivative and is considerably higher than the electroconductivity of a similar salt of unsubstituted iron bis(1,2-dicarbollide). The measurements of magnetic susceptibility at 2—300 K showed that this salt is paramagnetic.
作者简介
O. Kazheva
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: kosenko@ineos.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
A. Kravchenko
V. N. Karazin Kharkov National University
Email: kosenko@ineos.ac.ru
乌克兰, 4 pl. Svobody, Kharkov, 61022
G. Aleksandrov
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: kosenko@ineos.ac.ru
俄罗斯联邦, 31 Leninsky prosp., Moscow, 119991
I. Kosenko
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: kosenko@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
I. Lobanova
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: kosenko@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
V. Bregadze
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: kosenko@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
D. Chudak
V. N. Karazin Kharkov National University
Email: kosenko@ineos.ac.ru
乌克兰, 4 pl. Svobody, Kharkov, 61022
L. Buravov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: kosenko@ineos.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
S. Protasova
Institute of Solid State Physics, Russian Academy of Sciences
Email: kosenko@ineos.ac.ru
俄罗斯联邦, 2 ul. Akad. Osip´yana, Chernogolovka, Moscow Region, 142432
V. Starodub
Institute of Chemistry, Jan Kochanowski University in Kielce
Email: kosenko@ineos.ac.ru
波兰, 5 ul. Zeromskiego, Kielce, 25-369
O. Dyachenko
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: kosenko@ineos.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432