Electrochemical phosphorylation of coumarins catalyzed by transition metal complexes (Ni—Mn, Co—Mn)
- 作者: Strekalova S.1, Khrizanforov M.1, Gryaznova T.1, Khrizanforova V.1, Budnikova Y.1
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隶属关系:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- 期: 卷 65, 编号 5 (2016)
- 页面: 1295-1298
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238164
- DOI: https://doi.org/10.1007/s11172-016-1451-7
- ID: 238164
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详细
A possibility of electrochemical phosphorylation of coumarins (coumarin, 6-methylcoumarin, 7-methylcoumarin) with diethyl phosphite was shown. The approach is based on the oxidation of a mixture of the aromatic compound and diethyl phosphite (1: 1) under mild conditions (room temperature, atmospheric pressure) in the presence of a bimetallic catalytic systems: MnIIbipy/NiIIbipy and MnIIbipy/CoIIbipy (bipy is the 2,2´-bipyridine). This method allows one to obtain diethyl arylphosphonates in high yields (up to 70%) and 100% conversion of the phosphite.
作者简介
S. Strekalova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: khrizanforov@gmail.com
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088
M. Khrizanforov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: khrizanforov@gmail.com
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088
T. Gryaznova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: khrizanforov@gmail.com
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088
V. Khrizanforova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: khrizanforov@gmail.com
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088
Yu. Budnikova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: khrizanforov@gmail.com
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088