Terminal bis-acetylenes derived from 1,2-bis(1H-tetrazol-5-yl)ethane
- 作者: Ishmetova R.1, Yachevskii D.1,2, Ignatenko N.1, Slepukhin P.1, Efimov I.2, Bakulev V.2, Rusinov G.1,2, Filyakova V.1, Charushin V.1,2
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隶属关系:
- I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
- Ural State Technical University named after the first President of Russia B. N. Yeltsin
- 期: 卷 65, 编号 5 (2016)
- 页面: 1268-1271
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238111
- DOI: https://doi.org/10.1007/s11172-016-1446-4
- ID: 238111
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详细
The N(1)—N(1), N(2)—N(2), and N(1)—N(2) regioisomers of 1,2-bis[(prop-2-yn-1-yl)-1H-tetrazol-5-yl]ethane were first synthesized by alkylation of 1,2-bis(1H-tetrazol-5-yl)ethane with propargyl bromide. The peculiarities of the crystal structure of 1,2-bis[1-(prop-2-yn-1-yl)-1H-tetrazol-5-yl]ethane were evaluated by X-ray diffraction analysis. This compound is readily underwent Cu-catalyzed [3+2] cycloaddition with p-tolyl azide, p-nitrophenyl azide, and benzyl azide to give heterocyclic assembles bearing 1,2,3-triazole and tetrazole cycles. Catalyst-free [3+2] cycloadditions of 1,2-bis[1-(prop-2-yn-1-yl)-1H-tetrazol-5-yl]ethane and the mixtures of the N(1)—N(1), N(2)—N(2), N(1)—N(2) regioisomers with poly(glycidyl azide) oligomers resulted in 1,2,3-triazole cycles and crosslinking of the polymer chains.
作者简介
R. Ishmetova
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: vif@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620137
D. Yachevskii
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences; Ural State Technical University named after the first President of Russia B. N. Yeltsin
Email: vif@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620137; 19 ul. Mira, Ekaterinburg, 620002
N. Ignatenko
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: vif@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620137
P. Slepukhin
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: vif@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620137
I. Efimov
Ural State Technical University named after the first President of Russia B. N. Yeltsin
Email: vif@ios.uran.ru
俄罗斯联邦, 19 ul. Mira, Ekaterinburg, 620002
V. Bakulev
Ural State Technical University named after the first President of Russia B. N. Yeltsin
Email: vif@ios.uran.ru
俄罗斯联邦, 19 ul. Mira, Ekaterinburg, 620002
G. Rusinov
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences; Ural State Technical University named after the first President of Russia B. N. Yeltsin
Email: vif@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620137; 19 ul. Mira, Ekaterinburg, 620002
V. Filyakova
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: vif@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620137
V. Charushin
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences; Ural State Technical University named after the first President of Russia B. N. Yeltsin
Email: vif@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620137; 19 ul. Mira, Ekaterinburg, 620002