Phenylhydrosilocane as a source of silatranylium cations


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Quantum chemical calculations were used for comparative analysis of the cations of the atrane structure [M(OCH2CH2)3N]+ (M = Si or Ge) with classic three-coordinate cations R3M+ of Group 14 elements. The possibility of nuclear chemical generation of atranylium cations in the condensed phase was experimentally demonstrated with silatranylium ions as examples.

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T. Kochina

I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

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Email: t-kochina@mail.ru
俄罗斯联邦, 2 nab. Makarova, St. Petersburg, 199034

V. Avrorin

St. Petersburg State University

Email: t-kochina@mail.ru
俄罗斯联邦, 7/9 Universitetskaya nab., St. Petersburg, 198504

V. Fundamensky

St. Petersburg State Institute of Technology, Technical University

Email: t-kochina@mail.ru
俄罗斯联邦, 26 Moskovskii prosp., St. Petersburg, 190013

I. Ignatyev

St. Petersburg State University

Email: t-kochina@mail.ru
俄罗斯联邦, 7/9 Universitetskaya nab., St. Petersburg, 198504

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