Phenylhydrosilocane as a source of silatranylium cations
- 作者: Kochina T.A.1, Avrorin V.V.2, Fundamensky V.S.3, Ignatyev I.S.2
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隶属关系:
- I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
- St. Petersburg State University
- St. Petersburg State Institute of Technology, Technical University
- 期: 卷 65, 编号 4 (2016)
- 页面: 1047-1052
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/237847
- DOI: https://doi.org/10.1007/s11172-016-1411-2
- ID: 237847
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详细
Quantum chemical calculations were used for comparative analysis of the cations of the atrane structure [M(OCH2CH2)3N]+ (M = Si or Ge) with classic three-coordinate cations R3M+ of Group 14 elements. The possibility of nuclear chemical generation of atranylium cations in the condensed phase was experimentally demonstrated with silatranylium ions as examples.
作者简介
T. Kochina
I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: t-kochina@mail.ru
俄罗斯联邦, 2 nab. Makarova, St. Petersburg, 199034
V. Avrorin
St. Petersburg State University
Email: t-kochina@mail.ru
俄罗斯联邦, 7/9 Universitetskaya nab., St. Petersburg, 198504
V. Fundamensky
St. Petersburg State Institute of Technology, Technical University
Email: t-kochina@mail.ru
俄罗斯联邦, 26 Moskovskii prosp., St. Petersburg, 190013
I. Ignatyev
St. Petersburg State University
Email: t-kochina@mail.ru
俄罗斯联邦, 7/9 Universitetskaya nab., St. Petersburg, 198504
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