New organosilicon derivatives of some analytical reagents: sorbents and metallochromic agents
- 作者: Vlasova N.1, Oborina E.1, Belousova L.1, Larina L.1
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隶属关系:
- A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- 期: 卷 65, 编号 4 (2016)
- 页面: 1023-1026
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/237818
- DOI: https://doi.org/10.1007/s11172-016-1407-y
- ID: 237818
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详细
A synthesis of organosilicon monomeric and polymeric derivatives of 1,4-phenylenediamine, 4-aminoantipyrine, and aniline, which are analytical agents possessing sorption properties, was accomplished. The synthesized organosilicon polymers were studied as sorbents of heavy metals FeIII, HgII and noble metals AgI, AuIII, RhIII, PdII, PtIV. Poly[(3-N-silsesquioxanylpropyl-4aminoantipyrine)] exhibited high sorption activity with respect to platinum group metals in comparison with poly[N,N´-bis(3-silsesquioxanylpropyl)-1,4-phenylenediamine]. The reaction of poly[(3-N-silsesquioxanylpropyl-4-aminoantipyrine)] practically with all the elements under study was accompanied by coloring. The starting monomer exhibited similar metallochromic properties.
作者简介
N. Vlasova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: oborina@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033
E. Oborina
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: oborina@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033
L. Belousova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: oborina@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033
L. Larina
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: oborina@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033