New organosilicon derivatives of some analytical reagents: sorbents and metallochromic agents
- Autores: Vlasova N.1, Oborina E.1, Belousova L.1, Larina L.1
-
Afiliações:
- A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- Edição: Volume 65, Nº 4 (2016)
- Páginas: 1023-1026
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/237818
- DOI: https://doi.org/10.1007/s11172-016-1407-y
- ID: 237818
Citar
Resumo
A synthesis of organosilicon monomeric and polymeric derivatives of 1,4-phenylenediamine, 4-aminoantipyrine, and aniline, which are analytical agents possessing sorption properties, was accomplished. The synthesized organosilicon polymers were studied as sorbents of heavy metals FeIII, HgII and noble metals AgI, AuIII, RhIII, PdII, PtIV. Poly[(3-N-silsesquioxanylpropyl-4aminoantipyrine)] exhibited high sorption activity with respect to platinum group metals in comparison with poly[N,N´-bis(3-silsesquioxanylpropyl)-1,4-phenylenediamine]. The reaction of poly[(3-N-silsesquioxanylpropyl-4-aminoantipyrine)] practically with all the elements under study was accompanied by coloring. The starting monomer exhibited similar metallochromic properties.
Sobre autores
N. Vlasova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: oborina@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
E. Oborina
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: oborina@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
L. Belousova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: oborina@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
L. Larina
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: oborina@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033