Sorption of nitrogen-containing aromatic compounds on ultradispersed diamonds
- 作者: Lanin S.1, Rychkova S.1, Vinogradov A.1, Lanina K.1, Shatalov I.2
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隶属关系:
- Chemistry Department, M. V. Lomonosov Moscow State University
- CJSC Portlab
- 期: 卷 65, 编号 1 (2016)
- 页面: 110-119
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/236835
- DOI: https://doi.org/10.1007/s11172-016-1272-8
- ID: 236835
如何引用文章
详细
Adsorption of a number of aniline and pyridine derivatives from water-acetonitrile solution on ultradispersed diamonds was investigated using dynamic sorption method. It was shown that the nature of functional substitutes and their position in molecules of nitrogen-containing compounds of pyridine and aniline have a pronounced effect on adsorption on the surface of ultradispersed diamonds. The dependence of chromatographic sorbate retention on the content of mobile phase could be described by a curve with a minimum. Such nonlinear relationship was explained by the change in the ratio of contribution of specific and non-specific interaction to the sorbate retention that was observed on varying the volume content of an organic component in mobile phase. The influence of temperature on sorption of pyridine and aniline derivatives on ultradisperesed diamonds was investigated. The changes in enthalpy and entropy factors of competitive sorption of sorbates were determined.
作者简介
S. Lanin
Chemistry Department, M. V. Lomonosov Moscow State University
编辑信件的主要联系方式.
Email: SNLanin@phys.chem.msu.ru
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991
S. Rychkova
Chemistry Department, M. V. Lomonosov Moscow State University
Email: SNLanin@phys.chem.msu.ru
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991
A. Vinogradov
Chemistry Department, M. V. Lomonosov Moscow State University
Email: SNLanin@phys.chem.msu.ru
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991
K. Lanina
Chemistry Department, M. V. Lomonosov Moscow State University
Email: SNLanin@phys.chem.msu.ru
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991
I. Shatalov
CJSC Portlab
Email: SNLanin@phys.chem.msu.ru
俄罗斯联邦, c. Rumiancevo, Leninskiy District, Bisness-Park Rumyancevo, B, enter 15, 305B, Moscow Region, 142784