Nickel and palladium N-heterocyclic carbene complexes. Synthesis and application in cross-coupling reactions
- Авторы: Gafurov Z.1,2, Kantyukov A.2, Kagilev A.2, Balabayev A.2, Sinyashin O.1, Yakhvarov D.1,2
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Учреждения:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Kazan Federal University
- Выпуск: Том 66, № 9 (2017)
- Страницы: 1529-1535
- Раздел: Reviews
- URL: https://journals.rcsi.science/1066-5285/article/view/241173
- DOI: https://doi.org/10.1007/s11172-017-1920-7
- ID: 241173
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Аннотация
N-Heterocyclic carbenes (NHCs) are widely used as ligands in catalysis by transition metal complexes. The catalytic activity of transition metal NHC complexes is much higher than that of the transition metal complexes bearing the phosphine and nitrogen-containing ligands. They show excellent catalytic performance in different transformations of the organic compounds, especially in the carbon—carbon and carbon—element bond forming reactions. Palladium NHC complexes are very efficient catalysts for the cross-coupling reactions. On the other hand, nickel is less expensive and regarded as a promising alternative to palladium and, therefore, it attracts increasing attention from the researches. The present review is focused on the recent advances in the synthesis of N-heterocyclic carbene complexes of nickel and palladium and their application in catalysis of cross-coupling reactions of organic, organoelement and organometallic compounds with organic halides.
Об авторах
Z. Gafurov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Email: yakhvar@iopc.ru
Россия, 8 ul. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
A. Kantyukov
Kazan Federal University
Email: yakhvar@iopc.ru
Россия, 18 ul. Kremlyovskaya, Kazan, 420008
A. Kagilev
Kazan Federal University
Email: yakhvar@iopc.ru
Россия, 18 ul. Kremlyovskaya, Kazan, 420008
A. Balabayev
Kazan Federal University
Email: yakhvar@iopc.ru
Россия, 18 ul. Kremlyovskaya, Kazan, 420008
O. Sinyashin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yakhvar@iopc.ru
Россия, 8 ul. Arbuzova, Kazan, 420088
D. Yakhvarov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Автор, ответственный за переписку.
Email: yakhvar@iopc.ru
Россия, 8 ul. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008