Optimization of the key steps of synthesis and study of the fundamental physicochemical properties of high energy compounds — 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane

O. A. Luk´yanov; N. I. Shlykova; G. V. Pokhvisneva; T. V. Ternikova; S. V. Nikitin; G. A. Smirnov; Yu. V. Nelubina; P. V. Dorovatovskii; T. S. Kon´kova; N. V. Murav´yov; A. N. Pivkina

doi:10.1007/s11172-017-1855-z

Optimization of the key steps of synthesis and study of the fundamental physicochemical properties of high energy compounds — 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane

Авторы: Luk´yanov O.¹, Shlykova N.¹, Pokhvisneva G.¹, Ternikova T.¹, Nikitin S.¹, Smirnov G.¹, Nelubina Y.², Dorovatovskii P.³, Kon´kova T.⁴, Murav´yov N.⁴, Pivkina A.⁴
Учреждения:
1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
3. National Research Center “Kurchatov Institute”
4. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences
Выпуск: Том 66, № 6 (2017)
Страницы: 1066-1073
Раздел: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/240771
DOI: https://doi.org/10.1007/s11172-017-1855-z
ID: 240771

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Аннотация

The key steps of the synthesis of two high energy compounds, namely, 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane, were optimized. Their enthalpy of formation, density, impact and friction sensitivity, and thermal stability were experimentally determined.