Optimization of the key steps of synthesis and study of the fundamental physicochemical properties of high energy compounds — 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane

O. A. Luk´yanov; N. I. Shlykova; G. V. Pokhvisneva; T. V. Ternikova; S. V. Nikitin; G. A. Smirnov; Yu. V. Nelubina; P. V. Dorovatovskii; T. S. Kon´kova; N. V. Murav´yov; A. N. Pivkina

doi:10.1007/s11172-017-1855-z

Optimization of the key steps of synthesis and study of the fundamental physicochemical properties of high energy compounds — 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane

Authors: Luk´yanov O.A.¹, Shlykova N.I.¹, Pokhvisneva G.V.¹, Ternikova T.V.¹, Nikitin S.V.¹, Smirnov G.A.¹, Nelubina Y.V.², Dorovatovskii P.V.³, Kon´kova T.S.⁴, Murav´yov N.V.⁴, Pivkina A.N.⁴
Affiliations:
1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
3. National Research Center “Kurchatov Institute”
4. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences
Issue: Vol 66, No 6 (2017)
Pages: 1066-1073
Section: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/240771
DOI: https://doi.org/10.1007/s11172-017-1855-z
ID: 240771

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Abstract

The key steps of the synthesis of two high energy compounds, namely, 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane, were optimized. Their enthalpy of formation, density, impact and friction sensitivity, and thermal stability were experimentally determined.