Conversion of ferrous compounds in a flameless combustion wave of hexogen-based systems filled with iron formate and other additives
- Авторы: Mikhailov Y.1, Aleshin V.1, Kolesnikova A.1, Zhemchugova L.1, Maksimov Y.2
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Учреждения:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences
- Выпуск: Том 66, № 6 (2017)
- Страницы: 975-979
- Раздел: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240677
- DOI: https://doi.org/10.1007/s11172-017-1841-5
- ID: 240677
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Аннотация
The thermal decomposition of the energetic component and chemical reactions occurring at elevated temperatures in a flameless combustion wave of systems based on hexogen (filled with iron(II) formate and polyisocyanurate binding agent) afford a mixture of iron oxides and iron nitride as nanosized particles. The purposeful change in the ratio of the indicated basis components can provide individual Fe2O3, Fe3O4, or FeO in the conversion products. Additives of anthracene and hydroquinone to the initial composition can result in the formation of predominantly iron carbide in the products, whereas mainly iron nitrides are formed upon the addition of guanidine nitrate or 5-aminotetrazole. The addition of aluminum hydride components to the initial mixture results in the reduction of iron to the zero-valence state in the form of iron—aluminum intermetallic compounds.
Об авторах
Yu. Mikhailov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: vva@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
V. Aleshin
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: vva@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
A. Kolesnikova
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: vva@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
L. Zhemchugova
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: vva@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
Yu. Maksimov
N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences
Email: vva@icp.ac.ru
Россия, 4 ul. Kosygina, Moscow, 119991