Enviar artigo por via de e-mail Quantum-chemical modeling of possible reactions of Roussin’s red esters with aryl ligands in DMSO solution
- Autores: Emel’yanova N.S.1
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Afiliações:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Edição: Volume 67, Nº 8 (2018)
- Páginas: 1330-1334
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/242775
- DOI: https://doi.org/10.1007/s11172-018-2221-5
- ID: 242775
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Resumo
Possible reactions of Roussin’s red esters [Fe2(μ-SC6H4R)2(NO)4], where R = H, o-NH2, m-NO2, m-OH, or m-NH2, in DMSO solution were investigated by quantum chemical modeling. It was shown that in these systems, numerous reactions can occur, including NO donation, ligand substitution, and decomposition into mononuclear iron nitrosyl complexes. The resulting compounds are also NO donors.
Sobre autores
N. Emel’yanova
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Autor responsável pela correspondência
Email: n_emel@mail.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
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