Synthesis and characterization of new N-{4,6-bis[2-(het)arylvinyl]pyrimidin-2-yl}-substituted polycyclic aromatic imides
- Авторлар: Komissarova E.1,2, Vasyanin A.2, Zhulanov V.2, Lunegov I.2, Shklyaeva E.2, Abashev G.1,2
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Мекемелер:
- Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences
- Perm State University
- Шығарылым: Том 68, № 9 (2019)
- Беттер: 1702-1713
- Бөлім: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243475
- DOI: https://doi.org/10.1007/s11172-019-2614-0
- ID: 243475
Дәйексөз келтіру
Аннотация
Two series of new N-{4,6-bis[2-(het)arylvinyl]pyrimidin-2-yl}-substituted aromatic polycyclic imides were synthesized. The synthesized chromophores were characterized by UV and fluorescence spectroscopy, cyclic voltammetry, and quantum chemical density functional theory calculations. A change in the nature of aryl (hetaryl) moieties was found to cause changes in the optical properties of both solutions of these compounds and thin films prepared from these compounds. The replacement of the phthalimide moiety by the 1,8-naphthalimide one has led to a significant increase in the lowest unoccupied molecular orbital energy.
Авторлар туралы
E. Komissarova
Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences; Perm State University
Email: gabashev@psu.ru
Ресей, 3 ul. Akad. Koroleva, Perm, 614013; 15 ul. Bukireva, Perm, 614990
A. Vasyanin
Perm State University
Email: gabashev@psu.ru
Ресей, 15 ul. Bukireva, Perm, 614990
V. Zhulanov
Perm State University
Email: gabashev@psu.ru
Ресей, 15 ul. Bukireva, Perm, 614990
I. Lunegov
Perm State University
Email: gabashev@psu.ru
Ресей, 15 ul. Bukireva, Perm, 614990
E. Shklyaeva
Perm State University
Email: gabashev@psu.ru
Ресей, 15 ul. Bukireva, Perm, 614990
G. Abashev
Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences; Perm State University
Хат алмасуға жауапты Автор.
Email: gabashev@psu.ru
Ресей, 3 ul. Akad. Koroleva, Perm, 614013; 15 ul. Bukireva, Perm, 614990