(Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding
- Авторлар: Loginov D.1, Idrisov V.1, Nelyubina Y.1, Laskova Y.1, Kudinov A.1
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Мекемелер:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Шығарылым: Том 66, № 2 (2017)
- Беттер: 346-349
- Бөлім: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240062
- DOI: https://doi.org/10.1007/s11172-017-1738-3
- ID: 240062
Дәйексөз келтіру
Аннотация
A reaction of iodide [(η5-indenyl)IrI2]n (1) with thallium dicarbollide Tl[Tl(η-7,8-C2B9H11)] leads to (indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11) (2) in 32% yield. The X-ray diffraction study showed that in the structure of 2, the five-membered rings C5 and C2B3 have a cisoid conformation, in which the bridgehead carbon atoms of the indenyl ligand are arranged opposite to the carborane cage carbon atoms. The DFT calculations showed that the Ir—indenyl bond in compound 2 is weaker than the Ir—Cp bond in the complex (η-7,8-C2B9H11)IrCp.
Авторлар туралы
D. Loginov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: dloginov@ineos.ac.ru
Ресей, 28 ul. Vavilova, Moscow, 119991
V. Idrisov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: dloginov@ineos.ac.ru
Ресей, 28 ul. Vavilova, Moscow, 119991
Yu. Nelyubina
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: dloginov@ineos.ac.ru
Ресей, 28 ul. Vavilova, Moscow, 119991
Yu. Laskova
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: dloginov@ineos.ac.ru
Ресей, 28 ul. Vavilova, Moscow, 119991
A. Kudinov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: dloginov@ineos.ac.ru
Ресей, 28 ul. Vavilova, Moscow, 119991