Experimental determination of the standard enthalpy of formation of 4H,8H-bis(furazano)[3,4-b:3′,4′-e]pyrazine and evaluation of its performance as a dispersant of solid fuels
- Authors: Lempert D.B.1, Kazakov A.I.1, Sheremetev A.B.2, Gladyshkin A.G.2, Nabatova A.V.1, Yanovskii L.S.1,3
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Affiliations:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Department of Chemistry, M. V. Lomonosov Moscow State University
- Issue: Vol 68, No 10 (2019)
- Pages: 1856-1859
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243496
- DOI: https://doi.org/10.1007/s11172-019-2635-8
- ID: 243496
Cite item
Abstract
The energy of combustion ΔH°c of 4H,8H-bis(furazano)[3,4-b:3′,4′-e]pyrazine (BFP) was measured by calorimetry in the oxygen atmosphere and the standard enthalpy of formation ΔH°f was calculated. The real ΔH°f value was found to be 33 kJ mol−1 higher than reported before. The obtained results were used for correction of the evaluated efficiency of using BFP as a solid fuel dispersant for rocket ramjet engines, which showed high BFP performance.
About the authors
D. B. Lempert
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Author for correspondence.
Email: lempertdavid@yandex.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
A. I. Kazakov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: lempertdavid@yandex.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
A. B. Sheremetev
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: lempertdavid@yandex.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
A. G. Gladyshkin
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: lempertdavid@yandex.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
A. V. Nabatova
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: lempertdavid@yandex.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
L. S. Yanovskii
Institute of Problems of Chemical Physics, Russian Academy of Sciences; Department of Chemistry, M. V. Lomonosov Moscow State University
Email: lempertdavid@yandex.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432; Build. 3, 1 Leninskie Gory, Moscow, 119991
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