Email this article Perrhenate-ions adsorption by N-substituted chitosan derivatives
- Authors: Melchakova O.V.1, Pestov A.V.2,3, Pechishcheva N.V.1,3, Shunyaev K.Y.1,3
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Affiliations:
- Institute of Metallurgy, Ural Branch of Russian Academy of Sciences
- I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences
- Ural Federal University named after the first President of Russia B. N. Yeltsin
- Issue: Vol 68, No 3 (2019)
- Pages: 521-526
- Section: Full Article
- URL: https://journals.rcsi.science/1066-5285/article/view/243309
- DOI: https://doi.org/10.1007/s11172-019-2448-9
- ID: 243309
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Abstract
A comparative study of the sorption properties of N-(2-carboxyethyl)chitosan (CEC), N-(2-sulfoethyl)chitosan (SEC), N-(2,3-dihydroxy)propyl chitosan (HPC) and N-2-(2-pyridyl)ethyl chitosan (PEC) with respect to perrhenate ions in an acidic medium was carried out. On the basis of the analysis of the adsorption isotherms and the perrhenate ion adsorption degrees as functions of pH, it was found that the efficiency of adsorbents decreases in the sequence PEC > SEC > HPC > CEC. The investigated chitosan derivatives are characterized by a higher rate of sorption of perrhenate ions in comparison with known commercial anionites. In the case of PEC, accompanying ions have the least effect on the sorption.
About the authors
O. V. Melchakova
Institute of Metallurgy, Ural Branch of Russian Academy of Sciences
Author for correspondence.
Email: evdokimova_olga_@mail.ru
Russian Federation, 101 ul. Amundsena, Yekaterinburg, 620016
A. V. Pestov
I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences; Ural Federal University named after the first President of Russia B. N. Yeltsin
Email: evdokimova_olga_@mail.ru
Russian Federation, 22 ul. S. Kovalevskoi, Yekaterinburg, 620990; 19 ul. Mira, Yekaterinburg, 620002
N. V. Pechishcheva
Institute of Metallurgy, Ural Branch of Russian Academy of Sciences; Ural Federal University named after the first President of Russia B. N. Yeltsin
Email: evdokimova_olga_@mail.ru
Russian Federation, 101 ul. Amundsena, Yekaterinburg, 620016; 19 ul. Mira, Yekaterinburg, 620002
K. Yu. Shunyaev
Institute of Metallurgy, Ural Branch of Russian Academy of Sciences; Ural Federal University named after the first President of Russia B. N. Yeltsin
Email: evdokimova_olga_@mail.ru
Russian Federation, 101 ul. Amundsena, Yekaterinburg, 620016; 19 ul. Mira, Yekaterinburg, 620002
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