Email this article Complexation of tetrafluoroboric acid with benzo-15-crown-5
- Authors: Zhilov V.I.1, Kostikova G.V.1, Kuz´mina L.G.2, Demina L.I.1, Demin S.V.1, Tsivadze A.Y.1
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Affiliations:
- A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Issue: Vol 67, No 12 (2018)
- Pages: 2191-2194
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243215
- DOI: https://doi.org/10.1007/s11172-018-2354-6
- ID: 243215
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Abstract
The extraction of tetrafluoroboric acid from aqueous solutions to a solution of benzo-15-crown-5 (B15С5, 1 mol L-1) in chloroform is shown to occur due to complexation with the ratio of components HBF4: B15С5 = 1: 1.5. It was revealed by IR spectroscopy that the whole crown ether in the extract is coordinated. The 1: 1 HBF4•В15С5 complex was isolated and characterized using IR spectroscopy and X-ray diffraction analysis. The O(2) and O(4) atoms of the crown ether ring participate in the coordination.
About the authors
V. I. Zhilov
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Author for correspondence.
Email: zhilov@bk.ru
Russian Federation, Build. 4, 31 Leninsky prosp., Moscow, 199071
G. V. Kostikova
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: zhilov@bk.ru
Russian Federation, Build. 4, 31 Leninsky prosp., Moscow, 199071
L. G. Kuz´mina
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: zhilov@bk.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
L. I. Demina
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: zhilov@bk.ru
Russian Federation, Build. 4, 31 Leninsky prosp., Moscow, 199071
S. V. Demin
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: zhilov@bk.ru
Russian Federation, Build. 4, 31 Leninsky prosp., Moscow, 199071
A. Yu. Tsivadze
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: zhilov@bk.ru
Russian Federation, Build. 4, 31 Leninsky prosp., Moscow, 199071
