N -(2-Azidoethyl) derivatives of methylenebis(1-oxytriaz-1-ene 2-oxides)

G. A. Smirnov; P. B. Gordeev; S. V. Nikitin; G. V. Pokhvisneva; T. V. Ternikova; I. M. Chistokhvalov; O. A. Luk’yanov

doi:10.1007/s11172-018-2322-1

N-(2-Azidoethyl) derivatives of methylenebis(1-oxytriaz-1-ene 2-oxides)

Authors: Smirnov G.A.¹, Gordeev P.B.¹, Nikitin S.V.¹, Pokhvisneva G.V.¹, Ternikova T.V.¹, Chistokhvalov I.M.², Luk’yanov O.A.¹
Affiliations:
1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
2. D. Mendeleev University of Chemical Technology of Russia
Issue: Vol 67, No 11 (2018)
Pages: 2010-2015
Section: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/243162
DOI: https://doi.org/10.1007/s11172-018-2322-1
ID: 243162

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Abstract

A method for synthesizing new compounds capable of releasing NO within living organisms, namely, 2-azidoethyl derivatives of methylenebis(1-oxytriaz-1-ene 2-oxides) bearing one or few 2-azidoethyl moieties, was developed. The synthesis involves nucleophilic substitution of the bromine atoms of the parent 2-bromoethyl derivatives of methylenebis(1-oxytriaz-1-ene 2-oxides) with the azide group. Some of the synthesized compounds are of interest as promising energetic materials.