Email this article Polyvinyl chloride as a precursor for low-temperature synthesis of carbon materials
- Authors: Solodovnichenko V.S.1,2, Kryazhev Y.G.1,2, Arbuzov A.B.2, Talzi V.P.2, Antonicheva N.V.1,2, Drozdov V.A.1,2, Zapevalova E.S.2, Likholobov V.A.1,2
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Affiliations:
- Omsk Scientific Center of Siberian Branch of Russian Academy of Sciences
- Institute of Hydrocarbons Processing of Siberian Branch of Russian Academy of Sciences
- Issue: Vol 65, No 11 (2016)
- Pages: 2712-2717
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/239394
- DOI: https://doi.org/10.1007/s11172-016-1640-4
- ID: 239394
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Abstract
A method for carbon materials synthesis based on polyvinyl chloride has been proposed. Method includes polymer dehydrochlorination by alkali with carbon-rich conjugated structures (polyvinylenes) formation and its subsequent carbonization at relatively low temperatures. Raman and 13C NMR spectroscopy and transmission electron microscopy show that thermal treatment of the resulting polyvinylenes up to 400 °C leads to the formation of amorphous carbon material with chlorine contain less than 0.5 wt.%. These results can be used to develop dioxin-free technology of utilization of polyvinyl chloride and its wastes.
About the authors
V. S. Solodovnichenko
Omsk Scientific Center of Siberian Branch of Russian Academy of Sciences; Institute of Hydrocarbons Processing of Siberian Branch of Russian Academy of Sciences
Author for correspondence.
Email: vsolodovnichenko@gmail.com
Russian Federation, 15 prosp. Marksa, Omsk, 644024; 54 ul. Neftezavodskaya, Omsk, 644040
Yu. G. Kryazhev
Omsk Scientific Center of Siberian Branch of Russian Academy of Sciences; Institute of Hydrocarbons Processing of Siberian Branch of Russian Academy of Sciences
Email: vsolodovnichenko@gmail.com
Russian Federation, 15 prosp. Marksa, Omsk, 644024; 54 ul. Neftezavodskaya, Omsk, 644040
A. B. Arbuzov
Institute of Hydrocarbons Processing of Siberian Branch of Russian Academy of Sciences
Email: vsolodovnichenko@gmail.com
Russian Federation, 54 ul. Neftezavodskaya, Omsk, 644040
V. P. Talzi
Institute of Hydrocarbons Processing of Siberian Branch of Russian Academy of Sciences
Email: vsolodovnichenko@gmail.com
Russian Federation, 54 ul. Neftezavodskaya, Omsk, 644040
N. V. Antonicheva
Omsk Scientific Center of Siberian Branch of Russian Academy of Sciences; Institute of Hydrocarbons Processing of Siberian Branch of Russian Academy of Sciences
Email: vsolodovnichenko@gmail.com
Russian Federation, 15 prosp. Marksa, Omsk, 644024; 54 ul. Neftezavodskaya, Omsk, 644040
V. A. Drozdov
Omsk Scientific Center of Siberian Branch of Russian Academy of Sciences; Institute of Hydrocarbons Processing of Siberian Branch of Russian Academy of Sciences
Email: vsolodovnichenko@gmail.com
Russian Federation, 15 prosp. Marksa, Omsk, 644024; 54 ul. Neftezavodskaya, Omsk, 644040
E. S. Zapevalova
Institute of Hydrocarbons Processing of Siberian Branch of Russian Academy of Sciences
Email: vsolodovnichenko@gmail.com
Russian Federation, 54 ul. Neftezavodskaya, Omsk, 644040
V. A. Likholobov
Omsk Scientific Center of Siberian Branch of Russian Academy of Sciences; Institute of Hydrocarbons Processing of Siberian Branch of Russian Academy of Sciences
Email: vsolodovnichenko@gmail.com
Russian Federation, 15 prosp. Marksa, Omsk, 644024; 54 ul. Neftezavodskaya, Omsk, 644040
