Email this article Synthesis of gem-dichlorocyclopropane and 1,3-dioxane derivatives from divinylbenzene
- Authors: Raskil’dina G.Z.1, Borisova Y.G.1, Spirikhin L.V.2, Zlotskii S.S.1
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Affiliations:
- Ufa State Petroleum Technological University
- Ufa Federal Research Centre of the Russian Academy of Sciences
- Issue: Vol 68, No 11 (2019)
- Pages: 2092-2097
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243532
- DOI: https://doi.org/10.1007/s11172-019-2671-4
- ID: 243532
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Abstract
The Prins reaction and cyclopropanation of the light fraction obtained by distillation of the technical grade divinylbenzene and consisting of a mixture of 1,3- and 1,4-divinylbenzenes with admixture of 3- and 4-ethylstyrenes were studied. These reactions quantitatively give the corresponding gem-dichlorocyclopropane and 1,3-dioxane benzene derivatives. The structures of the synthesized compounds were confirmed by NMR spectroscopy and mass spectrometry.
About the authors
G. Z. Raskil’dina
Ufa State Petroleum Technological University
Author for correspondence.
Email: graskildina444@mail.ru
Russian Federation, 1 ul. Kosmonavtov, Ufa, 450062
Yu. G. Borisova
Ufa State Petroleum Technological University
Email: spectr@anrb.ru
Russian Federation, 1 ul. Kosmonavtov, Ufa, 450062
L. V. Spirikhin
Ufa Federal Research Centre of the Russian Academy of Sciences
Author for correspondence.
Email: spectr@anrb.ru
Russian Federation, 71 prosp. Oktyabrya, Ufa, Bashkortostan, 450054
S. S. Zlotskii
Ufa State Petroleum Technological University
Email: spectr@anrb.ru
Russian Federation, 1 ul. Kosmonavtov, Ufa, 450062
