The forces of symmetry and the physical meaning of the Pauli exclusion principle
- 作者: Smolenskii E.A.1
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隶属关系:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- 期: 卷 68, 编号 9 (2019)
- 页面: 1635-1639
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243466
- DOI: https://doi.org/10.1007/s11172-019-2605-1
- ID: 243466
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详细
A mathematically strict analysis of the consequences of the requirement of wave function antisymmetry is presented. It is shown that the probability density for symmetric electron configurations is zero, i.e., these electron configurations in atoms are inaccessible owing to the action of fundamental forces termed by the author “the forces of symmetry”. As a consequence, a fundamentally new, in computational aspect, quantum chemistry can be developed. A previously reported hypothesis that forbids two electrons with the same spins to have equal potentials is confirmed.
作者简介
E. Smolenskii
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: smolensk@ioc.ac.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991
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