Three-component synthesis of copper( ii ) coordination compounds with 2-hetarylbenzothiazoles

E. S. Barskaya; A. V. Rzheutskiy; A. A. Moiseeva; I. V. Yudin; N. V. Zyk; E. K. Beloglazkina

doi:10.1007/s11172-019-2499-y

Three-component synthesis of copper(ii) coordination compounds with 2-hetarylbenzothiazoles

Authors: Barskaya E.S.¹, Rzheutskiy A.V.¹, Moiseeva A.A.¹, Yudin I.V.¹, Zyk N.V.¹, Beloglazkina E.K.¹
Affiliations:
1. Department of Chemistry, M. V. Lomonosov Moscow State University
Issue: Vol 68, No 4 (2019)
Pages: 870-873
Section: Brief Communication
URL: https://journals.rcsi.science/1066-5285/article/view/243360
DOI: https://doi.org/10.1007/s11172-019-2499-y
ID: 243360

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Abstract

A method for synthesizing Cu^II coordination compounds with 2-hetaryl-substituted benzothiazoles was developed. The reactions of 2-amino-5-methoxythiophenol, 2-pyridyl- or 2(4)-imidazolylcarbaldehydes, and copper(ii) perchlorate in refluxing ethanol yield L₂Cu(ClO₄)₂ or L₃Cu(ClO₄)₂ complexes. According to the cyclic voltammetry data, the obtained copper coordination compounds can catalyze dismutation of superoxide anion.