Photogalvanic eff ect in porphyrin-pyrrolo[3′,4′:1,9]-(C 60 - I  h )[5,6]fullerene-2′,5′-dicarboxylate systems

D. V. Androsov; A. A. Strelnikov; A. S. Konev; D. A. Lukyanov; A. V. Kazakova; O. V. Levin; A. F. Khlebnikov

doi:10.1007/s11172-019-2491-6

Photogalvanic eff ect in porphyrin-pyrrolo[3′,4′:1,9]-(C₆₀-I_h)[5,6]fullerene-2′,5′-dicarboxylate systems

Authors: Androsov D.V.¹, Strelnikov A.A.¹, Konev A.S.¹, Lukyanov D.A.¹, Kazakova A.V.¹, Levin O.V.¹, Khlebnikov A.F.¹
Affiliations:
1. Institute of Chemistry, Saint Petersburg State University
Issue: Vol 68, No 4 (2019)
Pages: 825-831
Section: Full Article
URL: https://journals.rcsi.science/1066-5285/article/view/243352
DOI: https://doi.org/10.1007/s11172-019-2491-6
ID: 243352

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Abstract

The influence of molecular structural factors of covalently bound porphyrin-fullerene dyads and porphyrin—fullerene binary mixtures on photocurrent in model photoelectrochemical cells was studied. It was found that the photocurrent increased either by introducing solubilizing alkyl groups into the donor (porphyrin) or acceptor (fullerene) fragments, or by covalent binding porphyrin and fullerene into a donor-acceptor dyad.