New 2-(2-pyridyl)-substituted benzothiazoles with polyethylene glycol substituents
- Authors: Barskaya E.S.1, Shorokhov V.V.1, Rzheutsky A.V.1, Khudyakov A.D.1, Yudin I.V.1, Tafeenko V.A.1, Zyk N.V.1, Beloglazkina E.K.1
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Affiliations:
- Department of Chemistry, Lomonosov Moscow State University
- Issue: Vol 68, No 3 (2019)
- Pages: 638-643
- Section: Brief Communication
- URL: https://journals.rcsi.science/1066-5285/article/view/243329
- DOI: https://doi.org/10.1007/s11172-019-2468-5
- ID: 243329
Cite item
Abstract
An approach for the synthesis of new organic ligands combining in their structure pyridine, benzothiazole, and polyethylene glycol fragments was developed, proceeding from 6-hydroxy-2-(pyridin-2-yl)benzothiazole and mono- or ditosyl-substituted polyethylene glycols. The ligand 2-(2-{[2-(pyridin-2-yl)benzothiazol-6-yl]oxy}ethoxy)ethanol (L) in the reaction with Cu(ClO4)2•6 H2O and CuCl2•2 H2O formed coordination compounds of the composition L2Cu(ClO4)2•7 H2O and LCuCl2•0.5 H2O, respectively.
About the authors
E. S. Barskaya
Department of Chemistry, Lomonosov Moscow State University
Email: bel@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
V. V. Shorokhov
Department of Chemistry, Lomonosov Moscow State University
Email: bel@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
A. V. Rzheutsky
Department of Chemistry, Lomonosov Moscow State University
Email: bel@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
A. D. Khudyakov
Department of Chemistry, Lomonosov Moscow State University
Email: bel@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
I. V. Yudin
Department of Chemistry, Lomonosov Moscow State University
Email: bel@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
V. A. Tafeenko
Department of Chemistry, Lomonosov Moscow State University
Email: bel@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
N. V. Zyk
Department of Chemistry, Lomonosov Moscow State University
Email: bel@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
E. K. Beloglazkina
Department of Chemistry, Lomonosov Moscow State University
Author for correspondence.
Email: bel@org.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991