Email this article Synthesis of chloro(organo)silylmethyl-o-carboranes from organochlorosilanes and bromomagnesiummethyl-o-carboranes
- Authors: Izmaylov B.A.1, Vasnev V.A.1, Markova G.D.1
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Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 68, No 1 (2019)
- Pages: 121-124
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243287
- DOI: https://doi.org/10.1007/s11172-019-2426-2
- ID: 243287
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Abstract
An efficient method for the synthesis of 1-chloro(dimethyl)silylmethyl-o-carborane, 1-dichloro(methyl)silylmethyl-o-carborane, 1-trichlorosilylmethyl-o-carborane, and 1-trichlorosilylmethyl- 2-methyl-o-carborane using 1-bromomagnesiummethyl-o-carborane, 1-bromomagnesiummethyl-2-methyl-o-carborane, and organochlorosilanes was developed.
About the authors
B. A. Izmaylov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mgaly@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
V. A. Vasnev
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mgaly@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
G. D. Markova
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: mgaly@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
