Synthesis and photophysical properties of 2,3,4,5-tetraphenyl-1-n-octyl-1-monophosphole
- Authors: Petrov A.V.1, Zagidullin A.A.1, Burganov T.I.1, Shatalova N.I.2, Katsyuba S.A.1, Milyukov V.A.1
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Affiliations:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
- Kazan National Research Technological University
- Issue: Vol 68, No 2 (2019)
- Pages: 445-448
- Section: Brief Communications
- URL: https://journals.rcsi.science/1066-5285/article/view/243267
- DOI: https://doi.org/10.1007/s11172-019-2406-6
- ID: 243267
Cite item
Abstract
A new method for the preparation of 2,3,4,5-tetraphenyl-1-octyl-1-monophosphole was developed. It was shown that the reaction of n-octyl chloride with a mixture of sodium 1,2,3-tri-and 1-monophospholides obtained by refluxing sodium polyphosphides with diphenylacetylene resulted in the formation of exclusively 1-n-octyl-1-monophosphole. The photophysical properties of 1-n-octyl-1-monophosphole were studied by electron absorption and emission spectroscopy. According to the Raman spectroscopy data, the phenyl moieties of this molecule are efficiently conjugated with the diene system of the heterocycle leading to the appearance of the corresponding absorption and emission bands in the visible spectral range.
About the authors
A. V. Petrov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
Email: zagidullin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
A. A. Zagidullin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
Author for correspondence.
Email: zagidullin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
T. I. Burganov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
Email: zagidullin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
N. I. Shatalova
Kazan National Research Technological University
Email: zagidullin@iopc.ru
Russian Federation, 68 ul. K. Marksa, Kazan, 420015
S. A. Katsyuba
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
Email: zagidullin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
V. A. Milyukov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
Email: zagidullin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088