Synthesis of 4-(2-chloroethoxy)phenyl glycosides and their modification

N. N. Kondakov; M. V. Panova; P. I. Abronina; A. I. Zinin; A. M. Shpirt; L. O. Kononov

doi:10.1007/s11172-019-2402-x

Synthesis of 4-(2-chloroethoxy)phenyl glycosides and their modification

Authors: Kondakov N.N.¹, Panova M.V.¹, Abronina P.I.¹, Zinin A.I.¹, Shpirt A.M.¹, Kononov L.O.¹
Affiliations:
1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 2 (2019)
Pages: 416-423
Section: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/243263
DOI: https://doi.org/10.1007/s11172-019-2402-x
ID: 243263

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Abstract

4-(2-Chloroethoxy)phenyl (CEP) aglycon belongs to the class of Janus aglycons and has already been used as a pre-spacer in the synthesis of neoglycoconjugates and as a temporary protective group in the synthesis of oligosaccharides. In the present work, a set of glycosides of various monosaccharides containing CEP aglycon was synthesized. The possibility of modification of CEP aglycon was demonstrated using the corresponding lactoside as an example.