Aggregation behavior of the surfactant bearing pyrrolidinium head group in the presence of polyacrylic acid
- Authors: Vasilieva E.A.1, Lukashenko S.S.1, Vasileva L.A.1, Pavlov R.V.1, Gaynanova G.A.1, Zakharova L.Y.1
-
Affiliations:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
- Issue: Vol 68, No 2 (2019)
- Pages: 341-346
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243251
- DOI: https://doi.org/10.1007/s11172-019-2390-x
- ID: 243251
Cite item
Abstract
The aggregation characteristics of binary systems based on a novel pyrrolidinium surfactant with the hexadecyl hydrocarbon tail and hydroxyethyl fragment at the nitrogen atom were studied in the presence of polyacrylic acid by a complex of physicochemical methods (tensiometry, conductometry, dynamic light scattering, fluorescence spectroscopy, and spectrophotometry). The formation of surfactant–polyelectrolyte complexes leads to a decrease in the concentration thresholds of aggregation by an order of magnitude to form aggregates ~70 nm in size was established by tensiometry and fluorimetry. The solubilization capacity of the formed mixed aggregates was tested using the Orange OT hydrophobic dye.
About the authors
E. A. Vasilieva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
Author for correspondence.
Email: vasilevaelmira@mail.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
S. S. Lukashenko
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
Email: vasilevaelmira@mail.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
L. A. Vasileva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
Email: vasilevaelmira@mail.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
R. V. Pavlov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
Email: vasilevaelmira@mail.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
G. A. Gaynanova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
Email: vasilevaelmira@mail.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
L. Ya. Zakharova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”
Email: vasilevaelmira@mail.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088