Polyheteroarylenes based on 2,3,7,8-tetraaminodibenzo-p-dioxin and aromatic polyfunctional carboxylic acids


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Abstract

Polynaphthoylene benzimidazole and polybenzimidazole were obtained via polycondensation of 2,3,7,8-tetraaminodibenzo-p-dioxin with aromatic di- and tetracarboxylic acids in polyphosphoric acid. From a solution of polynaphthoylene benzimidazole in methanesulfonic acid a heat-resistant fiber with high tensile strength was obtained. Aromatic polybenzimidazoles are promising materials for producing membranes of medium-temperature fuel cells.

About the authors

D. M. Mognonov

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Author for correspondence.
Email: info@binm.ru
Russian Federation, 6 ul. Sakhyanovoy, Ulan-Ude, 670047

O. Zh. Ayurova

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Email: univer@bsu.ru
Russian Federation, 6 ul. Sakhyanovoy, Ulan-Ude, 670047

O. V. Il’ina

Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences

Email: univer@bsu.ru
Russian Federation, 6 ul. Sakhyanovoy, Ulan-Ude, 670047

V. V. Khakhinov

Buryat State University

Author for correspondence.
Email: univer@bsu.ru
Russian Federation, 24a ul. Smolina, Ulan-Ude, 670000


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