Supramolecular structuring of aqueous solutions of strong acids: manifestations in light scattering, NMR, and oxidation kinetics. Does liquid have a drop-like nature? 1. Nitric acid


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The properties of large (~100 nm), supramolecular assemblies in aqueous solutions of nitric acid were studied by light scattering methods. The dependence of structural characteristics on the solution composition, stability in time, and effects of temperature and mechanical impacts were determined. The previously obtained data on the structure of the reaction medium and kinetics of acetone oxidation in aqueous solutions of nitric acid were used in the discussion. The identified trends and features confirm the role of supramolecular structuring in the kinetic anomalies involved in acetone oxidation.

Sobre autores

G. Lagodzinskaya

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Autor responsável pela correspondência
Email: lago@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

T. Laptinskaya

Department of Physics, M. V. Lomonosov Moscow State University

Email: lago@icp.ac.ru
Rússia, Build. 2, 1 Leninskie Gory, Moscow, 119991

A. Kazakov

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: lago@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

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