Email this article Methane adsorption on various metal-organic frameworks and determination of the average adsorption heats at supercritical temperatures and pressures
- Authors: Pribylov A.A.1, Murdmaa K.O.1, Solovtsova O.V.1, Knyazeva M.K.1
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Affiliations:
- A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Issue: Vol 67, No 10 (2018)
- Pages: 1807-1813
- Section: Article
- URL: https://journals.rcsi.science/1066-5285/article/view/243077
- DOI: https://doi.org/10.1007/s11172-018-2293-2
- ID: 243077
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Abstract
Adsorption of methane on three samples of metal-organic framework structures (MOF), which contain copper, aluminum or zinc atoms, was measured at temperatures ranging from 303 to 333 K and pressures up to 40 MPa using a precise volumetric-gravimetric unit. The determined values of adsorption volumes and characteristic energies served to evaluate the average heats of adsorption, which were compared to the average isosteric heats of adsorption.
About the authors
A. A. Pribylov
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Author for correspondence.
Email: pribylov_34@mail.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
K. O. Murdmaa
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: pribylov_34@mail.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
O. V. Solovtsova
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: pribylov_34@mail.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
M. K. Knyazeva
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: pribylov_34@mail.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
