Hydrogenation of naphthalene and anthracene on Pt/C catalysts


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Abstract

Hydrogenation of naphthalene and anthracene deposited on Sibunit and active carbon was studied. The reactions were carried out at a temperature of 280 °C and a pressure of 90 atm. The directions for the complete hydrogenation of the investigated substrates were studied. Correlations between the structures of naphthalene and anthracene and their activity in hydrogen absorption are presented. The hydrogenation rates decrease as the substrate is saturated with hydrogen.

About the authors

A. N. Kalenchuk

Department of Chemistry, M. V. Lomonosov Moscow State University; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: akalenchuk@yandex.ru
Russian Federation, 1/3 Leninskie Gory, Moscow, 119991; 47 Leninsky prop., Moscow, 119991

A. E. Koklin

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: akalenchuk@yandex.ru
Russian Federation, 47 Leninsky prop., Moscow, 119991

V. I. Bogdan

Department of Chemistry, M. V. Lomonosov Moscow State University; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: akalenchuk@yandex.ru
Russian Federation, 1/3 Leninskie Gory, Moscow, 119991; 47 Leninsky prop., Moscow, 119991

L. M. Kustov

Department of Chemistry, M. V. Lomonosov Moscow State University; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: akalenchuk@yandex.ru
Russian Federation, 1/3 Leninskie Gory, Moscow, 119991; 47 Leninsky prop., Moscow, 119991

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