Synthesis of water-soluble bis- N , O -chelate nickel(II) complexes based on new ligands –  P -pyridyl-containing phospholane oxides

A. V. Shamsieva; K. R. Trigulova; R. R. Fayzullin; V. V. Khrizanforova; Yu. H. Budnikova; E. I. Musina; A. A. Karasik

doi:10.1007/s11172-018-2203-7

Synthesis of water-soluble bis-N,O-chelate nickel(II) complexes based on new ligands – P-pyridyl-containing phospholane oxides

Authors: Shamsieva A.V.¹, Trigulova K.R.¹, Fayzullin R.R.¹, Khrizanforova V.V.¹, Budnikova Y.H.¹, Musina E.I.¹, Karasik A.A.¹
Affiliations:
1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Issue: Vol 67, No 7 (2018)
Pages: 1206-1211
Section: Article
URL: https://journals.rcsi.science/1066-5285/article/view/242686
DOI: https://doi.org/10.1007/s11172-018-2203-7
ID: 242686

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Abstract

A series of new N,O-hybrid ligands was synthesized by oxidation of pyridyl-substituted phospholanes. These ligands were employed in the first synthesis of water-soluble mononuclear nickel(II) complexes [NiL₂(H₂O)₂](BF₄)₂ and [NiL₂(MeCN)₂](BF₄)₂. Physicochemical properties and crystalline structures of the synthesized compounds were thoroughly studied.