Email this article 1,4-cis-Hydrogenation of butyl sorbate in supercritical carbon dioxide
- Authors: Vasil’ev A.A.1, Kuchurov I.V.1, Zlotin S.G.1
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Affiliations:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Issue: Vol 67, No 5 (2018)
- Pages: 923-926
- Section: Brief Communications
- URL: https://journals.rcsi.science/1066-5285/article/view/242557
- DOI: https://doi.org/10.1007/s11172-018-2158-8
- ID: 242557
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Abstract
Hydrogenation of butyl sorbate into butyl Z-hex-3-enoate in supercritical carbon dioxide proceeds at high conversion and selectivity of 93–96% under catalysis with chromium hexacarbonyl at 180 °C and on using (methyl benzoate)chromium tricarbonyl as a catalyst at 160 °C.
About the authors
A. A. Vasil’ev
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: vasiliev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
I. V. Kuchurov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vasiliev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
S. G. Zlotin
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vasiliev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
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