Synthesis and characterization of biosynthetic polymers based on (2E)-3-(4-hydroxy-3-methoxy)-2-phenylpropenoic acid
- Authors: Karmanov A.P.1,2, Derkacheva O.Y.3, Kocheva L.S.2,4
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Affiliations:
- Institute of Biology, Komi Scientific Center, Ural Branch, Russian Academy of Sciences
- Pitirim Sorokin Syktyvkar State University
- St. Petersburg State University of Industrial Technology and Design, Higher School of Technology and Energetic
- Institute of Geology, Komi Scientific Center, Ural Branch, Russian Academy of Sciences
- Issue: Vol 67, No 5 (2018)
- Pages: 826-832
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/242504
- DOI: https://doi.org/10.1007/s11172-018-2144-1
- ID: 242504
Cite item
Abstract
The polymers obtained by the dehydrogenization enzymatic polymerization of (2E)-3-(4- hydroxy-3-methoxy)-2-phenylpropenoic acid (ferulic acid) in the peroxidase–hydrogen peroxide system were studied by 13С NMR and FTIR spectroscopy, elemental analysis, sedimentation diff usion analysis, and viscometry. The amount of the main structure fragments of the macromolecules was established, and comparative analysis of the chemical structures of the polymers was carried out. Differences in the topological structures of macromolecules of the biosynthetic polymers based on ferulic acid were revealed.
About the authors
A. P. Karmanov
Institute of Biology, Komi Scientific Center, Ural Branch, Russian Academy of Sciences; Pitirim Sorokin Syktyvkar State University
Author for correspondence.
Email: apk0948@yandex.ru
Russian Federation, 28 ul. Kommunisticheskaya, Syktyvkar, 167982; 55 Oktyabr’skii prosp., Syktyvkar, 167001
O. Yu. Derkacheva
St. Petersburg State University of Industrial Technology and Design, Higher School of Technology and Energetic
Email: apk0948@yandex.ru
Russian Federation, 4 ul. Ivana Chernykh, St. Petersburg, 198095
L. S. Kocheva
Pitirim Sorokin Syktyvkar State University; Institute of Geology, Komi Scientific Center, Ural Branch, Russian Academy of Sciences
Email: apk0948@yandex.ru
Russian Federation, 55 Oktyabr’skii prosp., Syktyvkar, 167001; 54 ul. Pervomaiskaya, Syktyvkar, 167982