Email this article Synthesis of cobalt bis(8-methylthio-1,2-dicarbollide)- pentacarbonyltungsten complexes
- Authors: Timofeev S.V.1, Anufriev S.A.1, Sivaev I.B.1, Bregadze V.I.1
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Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 67, No 3 (2018)
- Pages: 570-572
- Section: Brief Communications
- URL: https://journals.rcsi.science/1066-5285/article/view/242409
- DOI: https://doi.org/10.1007/s11172-018-2112-9
- ID: 242409
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Abstract
A reaction of Bu4N[8,8´-(MeS)2-3,3´-Co(1,2-C2B9H10)2] with (MeCN)3W(CO)3 in dichloromethane gave a mixture of Bu4N{(CO)5W[κ-8,8´-(MeS)2-3,3´-Co(1,2-C2B9H10)2]} and Bu4N{[(CO)5W]2[κ2-8,8´-(MeS)2-3,3´-Co(1,2-C2B9H10)2]}, which were separated by column chromatography on silica gel.
About the authors
S. V. Timofeev
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: sivaev@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
S. A. Anufriev
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: sivaev@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
I. B. Sivaev
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: sivaev@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
V. I. Bregadze
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: sivaev@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
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