New growth regulators of corn based on N-mono- and N,N-bis-3-butenyldichloroacetamides
- Authors: Bubnov Y.N.1,2, Spiridonov Y.Y.3, Kuznetsov N.Y.1
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Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Russian Research Institute of Phytopathology (VNIIF)
- Issue: Vol 67, No 2 (2018)
- Pages: 345-358
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/242222
- DOI: https://doi.org/10.1007/s11172-018-2080-0
- ID: 242222
Cite item
Abstract
Allylboration of imines, nitriles (including hydrocyanic acid), amides, lactams, aromatic azaheterocycles (pyridines, isoquinoline, and pyrrole) was used to synthesize a series of mono- and bis-3-butenylamines with different structures, which were converted to dichloroacetamides, new analogs of a known safener (herbicide antidote) Dichlormid successfully used in the cultivation of corn throughout the world. Biological tests for the germination of corn seeds showed that most of the dichloroacetamides obtained have growth-stimulating activity, which is mainly directed on the development of the root system. Compounds 2f, trans- and cis-2n, cis-2s, and 2t demonstrated outstanding activity, exceeding from two to three times the stimulating effect of Dichlormid on the developing root system of maize seedlings.
About the authors
Yu. N. Bubnov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: izvan@ioc.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991; 47 Leninsky prosp., Moscow, 119991
Yu. Ya. Spiridonov
Russian Research Institute of Phytopathology (VNIIF)
Email: izvan@ioc.ac.ru
Russian Federation, Vlad. 5 ul. Institut, Bol´shye Vyazyomy, Moscow Region, 143050
N. Yu. Kuznetsov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: izvan@ioc.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991