Отправить статью по E-mail Synthesis, structure, and magnetic properties of a YbIII complex with the iminopyridine radical-anionic ligand
- Авторы: Trifonov A.A.1,2, Shestakov B.G.2, Lyubov D.M.2, Lyssenko K.A.1
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Учреждения:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
- Выпуск: Том 67, № 1 (2018)
- Страницы: 50-55
- Раздел: Article
- URL: https://journals.rcsi.science/1066-5285/article/view/241904
- DOI: https://doi.org/10.1007/s11172-018-2036-4
- ID: 241904
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Аннотация
The reaction of equimolar amounts of ytterbocene (C5Me4H)2Yb(THF)2 and iminopyridine 2,6-Pri2C6H3N=CH(C5H4N) accompanied by the one-electron oxidation of the ytterbium ion produced the unique lanthanide complex (C5Me4H)2YbIII[2,6-Pri2-C6H3NCH(C5H4N)]–• with the iminopyridine radical-anionic ligand. The structure of the complex in the crystalline state was established by X-ray diffraction and its magnetic properties were studied in the temperature range of 1.8—300 K.
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Об авторах
A. Trifonov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: trif@iomc.ras.ru
Россия, 28 ul. Vavilova, Moscow, 119991; 49 ul. Tropinina, Nizhny Novgorod, 603137
B. Shestakov
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Email: trif@iomc.ras.ru
Россия, 49 ul. Tropinina, Nizhny Novgorod, 603137
D. Lyubov
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Email: trif@iomc.ras.ru
Россия, 49 ul. Tropinina, Nizhny Novgorod, 603137
K. Lyssenko
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: trif@iomc.ras.ru
Россия, 28 ul. Vavilova, Moscow, 119991
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