Aluminosilicates with different pores structure in the synthesis of 2,2,4-trimethyl-1,2-dihydroquinoline and N-phenyl-2-propanimine


Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Physicochemical characteristics of microporous zeolites of various structural type (FAU, BEA, MTW), micro-meso-macroporous zeolite (H-Ymmm), and mesoporous aluminosilicate (ASM) were studied. Their catalytic activity in the reaction of aniline with acetone was examined. It was found that 2,2,4-trimethyl-1,2-dihydroquinoline was the main reaction product on the catalysts H-Ymmm and ASM (selectivity up to 68% at 100% conversion of aniline), while the reaction on zeolites with microporous structure mainly gave N-phenyl-2-propanimine (selectivity up to 91%).

Авторлар туралы

N. Grigor’eva

Institute of Petrochemistry and Catalysis, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: ngg-ink@mail.ru
Ресей, 141 prosp. Oktyabrya, Ufa, 450075

N. Filippova

Institute of Petrochemistry and Catalysis, Russian Academy of Sciences

Email: ngg-ink@mail.ru
Ресей, 141 prosp. Oktyabrya, Ufa, 450075

A. Gataulin

Institute of Petrochemistry and Catalysis, Russian Academy of Sciences

Email: ngg-ink@mail.ru
Ресей, 141 prosp. Oktyabrya, Ufa, 450075

S. Bubennov

Institute of Petrochemistry and Catalysis, Russian Academy of Sciences

Email: ngg-ink@mail.ru
Ресей, 141 prosp. Oktyabrya, Ufa, 450075

M. Agliullin

Institute of Petrochemistry and Catalysis, Russian Academy of Sciences

Email: ngg-ink@mail.ru
Ресей, 141 prosp. Oktyabrya, Ufa, 450075

B. Kutepov

Institute of Petrochemistry and Catalysis, Russian Academy of Sciences

Email: ngg-ink@mail.ru
Ресей, 141 prosp. Oktyabrya, Ufa, 450075

Nama Narender

CSIR-Indian Institute of Chemical Technology Uppal Road

Email: ngg-ink@mail.ru
Үндістан, Tarnaka, Hyderabad, Telangana State, 500 007

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