Synthesis of thioether-containing carbosilane dendrimers with sterically shielded sulfur atoms
- Authors: Tarasenkov А.N.1, Getmanova E.V.1, Tatarinova E.A.1, Buzin М.I.2, Demchenko N.V.1, Cherkaev G.V.1, Muzafarov А.М.2
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Affiliations:
- N. S. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 66, No 9 (2017)
- Pages: 1675-1685
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/241299
- DOI: https://doi.org/10.1007/s11172-017-1940-3
- ID: 241299
Cite item
Abstract
Carbosilane thiols were synthesized as the first- and second-generation (in silicon) dendrons. It was demonstrated that the resulting bulky thiols successfully undergo the thiol—ene addition to third-generation polyallyl carbosilane dendrimer as a photoinitiated radical reaction to give the corresponding thioether-containing derivatives with sterically shielded sulfur atoms.
About the authors
А. N. Tarasenkov
N. S. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences
Author for correspondence.
Email: antarr@bk.ru
Russian Federation, 70 ul. Profsoyuznaya, Moscow, 117393
E. V. Getmanova
N. S. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences
Email: antarr@bk.ru
Russian Federation, 70 ul. Profsoyuznaya, Moscow, 117393
E. A. Tatarinova
N. S. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences
Email: antarr@bk.ru
Russian Federation, 70 ul. Profsoyuznaya, Moscow, 117393
М. I. Buzin
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: antarr@bk.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
N. V. Demchenko
N. S. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences
Email: antarr@bk.ru
Russian Federation, 70 ul. Profsoyuznaya, Moscow, 117393
G. V. Cherkaev
N. S. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences
Email: antarr@bk.ru
Russian Federation, 70 ul. Profsoyuznaya, Moscow, 117393
А. М. Muzafarov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: antarr@bk.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991