Email this article Novel olefin metathetis catalysts with fluorinated N-alkyl-N´-arylimidazolin-2-ylidene ligands
- Authors: Masoud S.M.1, Akmalov T.R.1, Artyushin O.I.1, Bruneau C.2, Osipov S.N.1
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Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
- CNRS -Universitŭ de Rennes 1, Institute des Sciences Chimique de Rennes, Organomŭtalliques: Matŭriaux et Catalyse, Centre for Catalysis and Green Chemistry, Campus de Beaulieau
- Issue: Vol 66, No 9 (2017)
- Pages: 1601-1606
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/241216
- DOI: https://doi.org/10.1007/s11172-017-1930-5
- ID: 241216
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Abstract
Novel ruthenium carbene complexes bearing unsymmetrical NHC-ligands based on N-alkyl-N´-arylimidazoline with hexafluoroisopropylmethoxy group in para-position of N-aryl moiety have been synthesized. Catalytic activity of complexes obtained was investigated on model reactions of intra- and intermolecular olefin metathesis.
About the authors
S. M. Masoud
A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Email: osipov@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
T. R. Akmalov
A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Email: osipov@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
O. I. Artyushin
A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Email: osipov@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
C. Bruneau
CNRS -Universitŭ de Rennes 1, Institute des Sciences Chimique de Rennes, Organomŭtalliques: Matŭriaux et Catalyse, Centre for Catalysis and Green Chemistry, Campus de Beaulieau
Email: osipov@ineos.ac.ru
France, Rennes, 35042
S. N. Osipov
A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Author for correspondence.
Email: osipov@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
