Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)
- Авторы: Barsukova M.O.1, Samsonenko D.G.1,2, Sapchenko S.A.1,2, Dybtsev D.N.1,2, Fedin V.P.1,2
- 
							Учреждения: 
							- A. B. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
 
- Выпуск: Том 66, № 8 (2017)
- Страницы: 1472-1477
- Раздел: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/241112
- DOI: https://doi.org/10.1007/s11172-017-1910-9
- ID: 241112
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Аннотация
The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.
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Об авторах
M. Barsukova
A. B. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
														Email: cluster@niic.nsc.ru
				                					                																			                												                	Россия, 							3 prosp. Akad. Lavrentyeva, Novosibirsk, 630090						
D. Samsonenko
A. B. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
														Email: cluster@niic.nsc.ru
				                					                																			                												                	Россия, 							3 prosp. Akad. Lavrentyeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090						
S. Sapchenko
A. B. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
														Email: cluster@niic.nsc.ru
				                					                																			                												                	Россия, 							3 prosp. Akad. Lavrentyeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090						
D. Dybtsev
A. B. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
														Email: cluster@niic.nsc.ru
				                					                																			                												                	Россия, 							3 prosp. Akad. Lavrentyeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090						
V. Fedin
A. B. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
							Автор, ответственный за переписку.
							Email: cluster@niic.nsc.ru
				                					                																			                												                	Россия, 							3 prosp. Akad. Lavrentyeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090						
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