Email this article Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)
- Authors: Barsukova M.O.1, Samsonenko D.G.1,2, Sapchenko S.A.1,2, Dybtsev D.N.1,2, Fedin V.P.1,2
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Affiliations:
- A. B. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Issue: Vol 66, No 8 (2017)
- Pages: 1472-1477
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/241112
- DOI: https://doi.org/10.1007/s11172-017-1910-9
- ID: 241112
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Abstract
The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.
About the authors
M. O. Barsukova
A. B. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentyeva, Novosibirsk, 630090
D. G. Samsonenko
A. B. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentyeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
S. A. Sapchenko
A. B. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentyeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
D. N. Dybtsev
A. B. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentyeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
V. P. Fedin
A. B. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Author for correspondence.
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentyeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
