Synthesis and study of optical properties of copolymers of perfluoro-2,2-dimethyl-1,3-dioxole and perfluoro(propyl vinyl ether)


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Polymerization under ultrahigh pressure without involvement of initiators was used to synthesize amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole and perfluoro(propyl vinyl ether). The copolymers have molecular masses within 2•104—7•104 au, possess high optical transparency in the telecom ranges of wavelength at 0.85, 1.3, and 1.5 μm and very low refractive index n = 1.293—1.314 at the wavelength λ = 632.8 nm. They can form films and are promising as claddings for optical fibers and waveguides. Amorphous films with the thickness of 1—4 μm were prepared by spin-coating from solutions of the perfluorinated copolymers in perfluorodecalin.

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V. Sokolov

Federal Scientific Research Centre “Crystallography and Photonics”, Russian Academy of Sciences

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Email: visokol@rambler.ru
俄罗斯联邦, 17A ul. Butlerova, Moscow, 117342

V. Boyko

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: visokol@rambler.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991

I. Goriachuk

Federal Scientific Research Centre “Crystallography and Photonics”, Russian Academy of Sciences

Email: visokol@rambler.ru
俄罗斯联邦, 17A ul. Butlerova, Moscow, 117342

S. Igumnov

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: visokol@rambler.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991

S. Molchanova

Federal Scientific Research Centre “Crystallography and Photonics”, Russian Academy of Sciences

Email: visokol@rambler.ru
俄罗斯联邦, 17A ul. Butlerova, Moscow, 117342

Yu. Pogodina

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: visokol@rambler.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991

E. Polunin

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: visokol@rambler.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991

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