Tetrathiafulvalene-based organic conductors with Pb-containing anions
- Авторлар: Zhilyaeva E.I.1, Torunova S.A.1, Shilov G.V.1, Flakina A.M.1, Yudanova E.I.1, Lyubovskaya R.N.1
- 
							Мекемелер: 
							- Institute of Problems of Chemical Physics, Russian Academy of Sciences
 
- Шығарылым: Том 66, № 6 (2017)
- Беттер: 986-990
- Бөлім: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240687
- DOI: https://doi.org/10.1007/s11172-017-1843-3
- ID: 240687
Дәйексөз келтіру
Аннотация
Hybrid compounds containing organic layers composed of tetrathiafulvalenes (BEDT-TTF, BETS, BEDO-TTF) and inorganic layers consisting of anions based on lead bromide were synthesized. The crystal structure of (BEDT-TTF)6Pb3Br10(PhBr) was determined. The temperature dependences of electrical conductivity for the synthesized compounds were measured and the EPR spectra of these compounds were recorded. In the structure of (BEDT-TTF)6Pb3Br10(PhBr), the organic conducting layers of BEDT-TTF molecules alternate with non-conducting layers composed of infinite chains of bromoplumbate anions [Pb3Br9]3–, solvent molecules, and Br– anions. The newly synthesized BEDT-TTF bromoplumbates have similar linewidths of EPR signals, which indicate that their conducting layers have similar structures. The BEDT-TTF bromoplumbates are semiconductors, while temperature-dependent electrical resistivity measurements show the metallic behavior for BEDO-TTF and BETS bromoplumbates.
Авторлар туралы
E. Zhilyaeva
Institute of Problems of Chemical Physics, Russian Academy of Sciences
							Хат алмасуға жауапты Автор.
							Email: zhilya@icp.ac.ru
				                					                																			                												                	Ресей, 							1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432						
S. Torunova
Institute of Problems of Chemical Physics, Russian Academy of Sciences
														Email: zhilya@icp.ac.ru
				                					                																			                												                	Ресей, 							1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432						
G. Shilov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
														Email: zhilya@icp.ac.ru
				                					                																			                												                	Ресей, 							1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432						
A. Flakina
Institute of Problems of Chemical Physics, Russian Academy of Sciences
														Email: zhilya@icp.ac.ru
				                					                																			                												                	Ресей, 							1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432						
E. Yudanova
Institute of Problems of Chemical Physics, Russian Academy of Sciences
														Email: zhilya@icp.ac.ru
				                					                																			                												                	Ресей, 							1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432						
R. Lyubovskaya
Institute of Problems of Chemical Physics, Russian Academy of Sciences
														Email: zhilya@icp.ac.ru
				                					                																			                												                	Ресей, 							1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432						
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