Email this article Synthesis and structure of ruthenium complexes [Ph3PCH2C6H4F-4]2[RuCl6] and [Ph3PCH2C6H4F-4][trans-RuCl4(dmso-S)2]
- Authors: Sharutin V.V.1, Sharutina O.K.1, Senchurin V.S.1, Kodess M.I.2
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Affiliations:
- South Ural State University
- I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
- Issue: Vol 66, No 6 (2017)
- Pages: 946-950
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240662
- DOI: https://doi.org/10.1007/s11172-017-1836-2
- ID: 240662
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Abstract
The reaction of (4-fluorobenzyl)triphenylphosphonium chloride with ruthenium(iii) chloride hydrate in the presence of hydrochloric acid in dimethyl sulfoxide affords the complex [Ph3PCH2C6H4F-4]2[RuCl6]. In the absence of hydrochloric acid, the reaction gives the complex [Ph3PCH2C6H4F-4][trans-RuCl4(dmso-S)2]. The structures of the complexes were studied by 1H, 19F, and 31P NMR spectroscopy and X-ray diffraction.
About the authors
V. V. Sharutin
South Ural State University
Author for correspondence.
Email: vvsharutin@rambler.ru
Russian Federation, 76 prosp. im. V. I. Lenina, Chelyabinsk, 454080
O. K. Sharutina
South Ural State University
Email: vvsharutin@rambler.ru
Russian Federation, 76 prosp. im. V. I. Lenina, Chelyabinsk, 454080
V. S. Senchurin
South Ural State University
Email: vvsharutin@rambler.ru
Russian Federation, 76 prosp. im. V. I. Lenina, Chelyabinsk, 454080
M. I. Kodess
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: vvsharutin@rambler.ru
Russian Federation, 22 ul. S. Kovalevskoi, Ekaterinburg, 620990
