Synthesis of new alkoxysilyl-substituted carboranes
- Authors: Izmaylov B.A.1, Vasnev V.A.1, Bregadze V.I.1, Rodlovskaya E.N.1, Markova G.D.1
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Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 66, No 5 (2017)
- Pages: 899-902
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240606
- DOI: https://doi.org/10.1007/s11172-017-1826-4
- ID: 240606
Cite item
Abstract
New 1,7-bis(trialkoxysilylpropyl)-m-carboranedicarboxamides were synthesized by the reaction of 3-aminopropyltrialkoxysilanes with either m-carboranedicarboxylic acid chloride in the presence of Et3N or m-carboranedicarboxylic acid in the presence of N,N´-carbonyl-diimidazole. The synthesized compounds are colorless liquids soluble in benzene, toluene, tetrahydrofuran, diethyl ether, and chloroform and insoluble in water. Structures of the synthesized compounds were established by IR and NMR spectroscopy and confirmed by elemental analysis. The synthesized compounds are interesting starting materials for produc-tion of heat-resistant silicon carborane polymers and metal-carborane-silicon polymers.
About the authors
B. A. Izmaylov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mgaly@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
V. A. Vasnev
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mgaly@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
V. I. Bregadze
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mgaly@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
E. N. Rodlovskaya
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mgaly@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
G. D. Markova
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: mgaly@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991