Synthesis, structure, and properties of compounds containing both octahedral rhenium cluster cations and anions
- Authors: Ivanov A.A.1, Shestopalov M.A.1,2, Brylev K.A.1,2, Vorotnikov Y.A.1, Plyusnin P.E.1,2, Mironov Y.V.1,2
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Affiliations:
- A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Issue: Vol 66, No 3 (2017)
- Pages: 426-431
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240128
- DOI: https://doi.org/10.1007/s11172-017-1750-7
- ID: 240128
Cite item
Abstract
The compound [{Re6S8}(3,5-Me2pzH)6]2[{Re6S8}Br6]•9H2O•4EtOH containing a cluster cation and a cluster anion in a 2: 1 ratio was synthesized by mixing an ethanol solution of the rhenium cluster complex [{Re6S8}(3,5-Me2pzH)6]Br2•2(3,5-Me2pzH) (pzH is pyrazole) with an aqueous solution of Cs4[{Re6S8}Br6]•2H2O. The resulting compound was characterized by a combination of physicochemical methods. In particular, luminescence properties were studied and compared with those of the parent cluster complexes. A crystal suitable for single-crystal X-ray diffraction was obtained by layering these solutions. According to single-crystal X-ray diffraction analysis, this compound is composed of a cluster cation and a cluster anion (in a ratio of 1: 1) and also of Zundel cations (H5O2+) and solvate water molecules and is described by the formula (H5O2)2[{Re6S8}(3,5-Me2pzH)6][{Re6S8}Br6]•4H2O.
About the authors
A. A. Ivanov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: niic@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090
M. A. Shestopalov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Author for correspondence.
Email: niic@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
K. A. Brylev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: niic@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
Yu. A. Vorotnikov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: niic@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090
P. E. Plyusnin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: niic@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
Yu. V. Mironov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: niic@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090