Unusual transformation of 3-alkylfuroxans into 3-(nitrooxyalkyl)furoxans on treatment with a mixture of nitric and sulfuric acids

V. A. Ogurtsov; A. V. Shastin; S. G. Zlotin; O. A. Rakitin

doi:10.1007/s11172-016-1675-6

Unusual transformation of 3-alkylfuroxans into 3-(nitrooxyalkyl)furoxans on treatment with a mixture of nitric and sulfuric acids

作者: Ogurtsov V.A.¹, Shastin A.V.², Zlotin S.G.¹, Rakitin O.A.¹
隶属关系:
1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
2. Institute of Problems of Chemical Physics, Russian Academy of Sciences
期: 卷 65, 编号 12 (2016)
页面: 2901-2906
栏目: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/239594
DOI: https://doi.org/10.1007/s11172-016-1675-6
ID: 239594

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详细

A versatile one-pot synthesis of 4-substituted 3-(nitrooxyalkyl)furoxans by the reaction of 3-alkylfuroxans with a mixture of nitric and sulfuric acids was developed. A plausible mechanism of this unusual transformation was explained in terms of a new Grob-type fragmentation.